Tuned selectivity and enhanced activity of CO₂methanation over Ru catalysts by modified metal–carbonate interfaces

Qiaojuan Wang^a, Yating Gao^a, Chantsalmaa Tumurbaatar^a, Tungalagtamir Bold^b,FeiWei^c,Yihu Dai^a,*, Yanhui Yang^a,*

^aInstitute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816,Jiangsu, China

^bSchool of Applied Sciences, Mongolian University of Science and Technology, Ulaanbaatar 14191, Mongolia

^cBeijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Abstract:

Ru/MnCO₃catalyst with metal-carbonates interfaces exhibits superior catalytic selectivity and anti-CO stability in CO₂methanation in comparison with Ru/MnO catalyst, benefiting from enhanced CO₂and H₂dissociation, formation of active Ru–CO* intermediates, and further rapid transformation into CH₄.

Journal of Energy Chemistry 64 (2022) 38–46.

(中国科技期刊卓越行动计划重点期刊，影响因子：7.216)

论文链接：https://doi.org/10.1016/j.jechem.2021.04.039