Small Molecule Activation by Uranium complexes : Examples of Synergistic Effects
报告人:Prof. Laurent Maron
报告时间:2023年7月18日(星期二)上午10:00
报告地点:笃学楼302会议室
报告人简介:
Laurent Maron教授,1999年获得法国图卢兹大学理论化学和瑞典斯德哥尔摩大学理论物理博士学位;1999-2001在法国Montpellier大学Prof. O. Eisenstein团队中进行博士后研究工作;2001-至今,在法国图卢兹大学的物理化学系开展独立科研工作,从事过渡金属及其配合物催化反应机理方面的研究。在Science, Nat. Chem., Acc. Chem. Res., PNAS, J. Am. Chem. Soc., Angew. Chem. Int. Edit.等国际期刊上发表论文564篇,个人H因子为73。获得的荣誉包括:SeniorMemberoftheInstitutUniversitairedeFrance, Chinese Academy of Science award (2015, 2019), Humboldt fellowship (2018), RSC-SCF award (2018)。
报告摘要:In this presentation, we will focus on the performance of an efficient interplay between experience and theory to elucidate the reactivity of actinide-catalyzed small molecule activation reactions. Based on the theoretical description of N2activation to yield Ammonia or O2activation, we will demonstrate that synergistic effects between Uranium(III) and transition metal but also with non-metal, such as phosphorus, allow facile direct full activation of N2and O2under ambient conditions.